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Reversible deactivation radical polymerization initiators

A well controlled RDRP process requires: 1) the reversible deactivation process should be sufficiently fast; 2) the chain breaking reactions which cause the loss of chain end functionalities should be limited; 3) properly maintained radical concentration; 4) the initiator should have proper activity. History and character - Reversible-deactivation - Common features - Examples. In the case of reversible deactivation radical polymerization (RDRP), a majority of chain must be held in a dormant state to ensure that the concentration of active carriers is sufficiently low as to render chain termination reactions negligible. Reversible-deactivation radical polymerization of chloroprene and the synthesis of novel in benzene using 2,2′-azobis(isobutyronitrile) (AIBN) as initiator. In order to further explore the potential of thiolactone chemistry for the field of reversible-deactivation radical polymerization (RDRP), we have.

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